| Autor: |
Galluzzo MD; Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, United States.; Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States., Loo WS; Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, United States., Schaible E; Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States., Zhu C; Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States., Balsara NP; Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, United States.; Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.; Joint Center for Energy Storage Research (JCESR), Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States. |
| Abstrakt: |
An important consideration when designing lithium battery electrolytes for advanced applications is how the electrolyte facilitates ion transport at fast charge and discharge rates. Large current densities are accompanied by large salt concentration gradients across the electrolyte. Nanostructured composite electrolytes have been proposed to enable the use of high energy density lithium metal anodes, but many questions about the interplay between the electrolyte morphology and the salt concentration gradient that forms under dc polarization remain unanswered. To address these questions, we use an in situ small-angle X-ray scattering technique to examine the nanostructure of a polystyrene- block -poly(ethylene oxide) copolymer electrolyte under dc polarization with spatial and temporal resolution. In the quiescent state, the electrolyte exhibits a lamellar morphology. The passage of ionic current in a lithium symmetric cell leads to the formation of concurrent phases: a disordered morphology near the negative electrode, lamellae in the center of the cell, and coexisting lamellae and gyroid near the positive electrode. The most surprising result of this study was obtained after the applied electric field was turned off: a current-induced gyroid phase grows in volume for 6 h in spite of the absence of an obvious driving force. We show that this reflects the formation of localized pockets of salt-dense electrolyte, termed concentration hotspots, under dc polarization. Our methods may be applied to understand the dynamic structure of composite electrolytes at appreciable current densities. |
