Enhanced hydrogen production from catalytic biomass gasification with in-situ CO 2 capture.

Autor: Wang J; School of Energy and Environmental Engineering, Key Laboratory of Clean Energy Utilization and Pollutant Control in Tianjin, Hebei University of Technology, China., Kang D; School of Energy and Environmental Engineering, Key Laboratory of Clean Energy Utilization and Pollutant Control in Tianjin, Hebei University of Technology, China., Shen B; School of Energy and Environmental Engineering, Key Laboratory of Clean Energy Utilization and Pollutant Control in Tianjin, Hebei University of Technology, China., Sun H; School of Chemistry and Chemical Engineering, Queens University Belfast, Belfast, Northern Ireland, BT7 1NN, United Kingdom., Wu C; School of Energy and Environmental Engineering, Key Laboratory of Clean Energy Utilization and Pollutant Control in Tianjin, Hebei University of Technology, China; School of Chemistry and Chemical Engineering, Queens University Belfast, Belfast, Northern Ireland, BT7 1NN, United Kingdom. Electronic address: c.wu@qub.ac.uk.
Jazyk: angličtina
Zdroj: Environmental pollution (Barking, Essex : 1987) [Environ Pollut] 2020 Dec; Vol. 267, pp. 115487. Date of Electronic Publication: 2020 Sep 08.
DOI: 10.1016/j.envpol.2020.115487
Abstrakt: In order to cope with the global energy crisis and environmental pollution problems, there are urgent needs for clean energy such as biomass-derived hydrogen. CaO is effective to promote hydrogen production from biomass gasification due to its high capacity of in-situ CO 2 capture. In this work, a two-stage fixed bed reactor was used to produce hydrogen by catalytic conversion of biomass with and without in-situ CO 2 capture. In addition, three Ni loadings (5 wt%, 10 wt%, and 20 wt%) supported by Al 2 O 3 and sol-gel CaO have been prepared and tested. The BET analysis shows the surface area of the catalysts increases first and then decreases with the increase of Ni loading. Results from high-resolution transmission electron microscopy (HRTEM) images reveals that NiO particles are well distributed over the porous CaO. The X-ray diffraction (XRD) analysis indicates the NiO nanocrystalline size is increased with increasing Ni loading on Ni/Al 2 O 3 , and the most homogeneous dispersion was shown by 10 wt% Ni/CaO. Around 666 mgCO 2 /gCaO of CO 2 adsorption capacity and 850 min stability were obtained using the sol-gel CaO sorbent. Compared to the reference Ni/Al 2 O 3 catalysts, the resistance of carbon deposition on the Ni/CaO results in a lower coke deposition, which is attributed to the basicity of the catalysts. In addition, the increase of loading promotes the decomposition of biomass-derived oxygenated compounds. Much more hydrogen is obtained using the Ni/CaO catalysts compared with Ni/Al 2 O 3 due to in-situ CO 2 capture. However, the sintering and particle agglomeration using the 20 wt% Ni-catalyst might be responsible for the reduction of hydrogen production. The highest H 2 concentration of 19.32 vol% at 424 °C was obtained when the 10 wt% Ni/CaO catalyst was used.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2020 Elsevier Ltd. All rights reserved.)
Databáze: MEDLINE
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