| Autor: |
Hadi JM; Department of Medical Laboratory of Science, College of Health Sciences, University of Human Development, Kurdistan Regional Government, Sulaimani 46001, Iraq., Aziz SB; Hameed Majid Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Iraq.; Department of Civil Engineering, College of Engineering, Komar University of Science and Technology, Sulaimani 46001, Iraq., R Saeed S; Charmo Research Center, Charmo University, Peshawa Street, Chamchamal, Sulaimani 46023, Iraq., Brza MA; Hameed Majid Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Iraq.; Department of Manufacturing and Materials Engineering, Faculty of Engineering, International Islamic University of Malaysia, Kuala Lumpur 53100, Malaysia., Abdulwahid RT; Hameed Majid Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Iraq.; Department of Physics, College of Education, Old Campus, University of Sulaimani, Kurdistan Regional Government, Sulaimani 46001, Iraq., Hamsan MH; Centre for Foundation Studies in Science, University of Malaya, Kuala Lumpur 50603, Malaysia., M Abdullah R; Hameed Majid Advanced Polymeric Materials Research Lab., Department of Physics, College of Science, University of Sulaimani, Qlyasan Street, Sulaimani 46001, Iraq., Kadir MFZ; Centre for Foundation Studies in Science, University of Malaya, Kuala Lumpur 50603, Malaysia., Muzakir SK; Material Technology Program, Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak, Gambang, Kuantan 43600, Malaysia. |
| Abstrakt: |
In this study, biopolymer composite electrolytes based on chitosan:ammonium iodide:Zn(II)-complex plasticized with glycerol were successfully prepared using the solution casting technique. Various electrical and electrochemical parameters of the biopolymer composite electrolytes' films were evaluated prior to device application. The highest conducting plasticized membrane was found to have a conductivity of 1.17 × 10 -4 S/cm. It is shown that the number density, mobility, and diffusion coefficient of cations and anions fractions are increased with the glycerol amount. Field emission scanning electron microscope and Fourier transform infrared spectroscopy techniques are used to study the morphology and structure of the films. The non-Debye type of relaxation process was confirmed from the peak appearance of the dielectric relaxation study. The obtained transference number of ions (cations and anions) and electrons for the highest conducting sample were identified to be 0.98 and 0.02, respectively. Linear sweep voltammetry shows that the electrochemical stability of the highest conducting plasticized system is 1.37 V. The cyclic voltammetry response displayed no redox reaction peaks over its entire potential range. It was discovered that the addition of Zn(II)-complex and glycerol plasticizer improved the electric double-layer capacitor device performances. Numerous crucial parameters of the electric double-layer capacitor device were obtained from the charge-discharge profile. The prepared electric double-layer capacitor device showed that the initial values of specific capacitance, equivalence series resistance, energy density, and power density are 36 F/g, 177 Ω, 4.1 Wh/kg, and 480 W/kg, respectively. |
