Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents.
| Autor: | Moaven S; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Watson BT; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Thompson SB; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Lyons VJ; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Unruh DK; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Casadonte DJ; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Pappas D; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu., Cozzolino AF; Department of Chemistry and Biochemistry , Texas Tech University , Box 41061 , Lubbock , Texas 79409-1061 , USA . Email: Anthony.f.cozzolino@ttu.edu. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical science [Chem Sci] 2020 Apr 09; Vol. 11 (17), pp. 4374-4380. Date of Electronic Publication: 2020 Apr 09 (Print Publication: 2020). |
| DOI: | 10.1039/d0sc00206b |
| Abstrakt: | A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles. Structural data reveals that pnictogen bonding drives the self-assembly of these molecules into a reversed bilayer. The ability to make these hollow, spherical, and chemically and temporally stable vesicles that can be broken and reformed by sonication allows these systems to be used for encapsulation and compartmentalisation in organic media. This was demonstrated through the encapsulation and characterization of several small organic reporter molecules. (This journal is © The Royal Society of Chemistry 2020.) |
| Databáze: | MEDLINE |
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