Induction of Chirality in a Metal-Organic Framework Built from Achiral Precursors.

Autor: Wu D; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.; Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China., Zhou K; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China., Tian J; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.; Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China., Liu C; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China., Tian J; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.; Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou, 450001, China., Jiang F; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China., Yuan D; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China., Zhang J; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China., Chen Q; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China., Hong M; State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2021 Feb 08; Vol. 60 (6), pp. 3087-3094. Date of Electronic Publication: 2020 Dec 21.
DOI: 10.1002/anie.202013885
Abstrakt: Induction of chirality from an achiral assembly system remains a huge challenge related to the origin of life. Here, induction of chirality in a metal-organic framework (MOF) built from achiral precursors has been realized. Assembling achiral H 3 BTB ligands and Zn II /Cd II clusters leads to a 2D coordination polymer (FJI-H16), while introduction of achiral pyridine into such assembly system leads to a 3D chiral MOF (FJI-H27 (M) or (P)). The driven force for chiral generation has been proved to be a pyridine participated kinetic-control assembly process, which can be controlled by changing the amount of pyridine and temperature, from no induction to partial induction to complete induction. The chiral generation process has been identified in detail through a pyridine-involved key intermediate (FJI-H28). The targeted modification of pyridine can selectively lead to FJI-H27 (M) or FJI-H27 (P), making the chiral orientation and distribution of bulk FJI-H27 samples can be controlled. Our work not only represents a new chiral induction process that may relate to the chiral origin in nature, but also firstly reveals how achiral external stimuli generate chirality from achiral precursors, and offers a guide for rational preparation of chiral MOFs.
(© 2020 Wiley-VCH GmbH.)
Databáze: MEDLINE
Externí odkaz: