Dielectric and material analysis on physicochemical activity of porous hydroxyapatite/cornstarch composites.

Autor: Beh CY; Faculty of Electronic Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia., Cheng EM; Advanced Communication Engineering, Centre of Excellence (CoE), Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia.; Faculty of Electronic Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia.. Electronic address: emcheng@unimap.edu.my., Mohd Nasir NF; Faculty of Electronic Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia., Eng SK; Faculty of Electrical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia., Abdul Majid MS; Faculty of Mechanical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia., Ridzuan MJM; Faculty of Mechanical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia., Khor SF; Faculty of Electrical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia., Khalid NS; Faculty of Electrical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Perlis, Malaysia.
Jazyk: angličtina
Zdroj: International journal of biological macromolecules [Int J Biol Macromol] 2021 Jan 01; Vol. 166, pp. 1543-1553. Date of Electronic Publication: 2020 Nov 09.
DOI: 10.1016/j.ijbiomac.2020.11.034
Abstrakt: This paper provides a comprehensive analysis of the dielectric and physicochemical properties of the porous hydroxyapatite/cornstarch (HAp/Cs) composites in a new perspective. The porous composites have been characterized via SEM, FTIR, XRD and dielectric spectroscopy. The dielectric permittivity spectra were obtained in Ku-band (12.4-18.0 GHz) and it was correlated with the physicochemical properties of the porous HAp/Cs. Porous HAp/Cs composites exhibits low ε' and negative ε″, which influenced by the microstructural morphology, interaction between Hap and Cs, as well as crystalline features due to the various proportion of the HAp/Cs. The physicochemical effect of the composites results in the dielectric polarization and energy loss. This phenomenon indicates the presence of the three obvious relaxation responses in the ε' spectrum (13.2-14.0, 15.2-16.0, and 16.6-17.4 GHz) and the negative behaviours in the ε″ spectrum. The relationships between physicochemical and dielectric properties of the porous composite facilitate the development of the non-destructive microwave evaluation test for the porous composite.
(Copyright © 2020 Elsevier B.V. All rights reserved.)
Databáze: MEDLINE
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