| Autor: |
Drzewicz P; Polish Geological Institute-National Research Institute, Rakowiecka 4, 00-975, Warszawa, Poland. przemyslaw.drzewicz@pgi.gov.pl., Naglik B; Polish Geological Institute-National Research Institute, Upper Silesian Branch, Królowej Jadwigi 1, 41-200, Sosnowiec, Poland., Natkaniec-Nowak L; AGH UST, University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Mickiewicza 30, 30-059, Kraków, Poland., Dumańska-Słowik M; AGH UST, University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Mickiewicza 30, 30-059, Kraków, Poland., Stach P; AGH UST, University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Mickiewicza 30, 30-059, Kraków, Poland., Kwaśny M; Institute of Optoelectronics, Military University of Technology, Gen. S. Kaliskiego 2, 00-908, Warszawa, Poland., Matusik J; AGH UST, University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Mickiewicza 30, 30-059, Kraków, Poland., Milovský R; Earth Science Institute, Slovak Academy of Sciences, Ďumbierska 1, 974 11, Banská Bystrica, Slovakia., Skonieczny J; Łukasiewicz Research Network-Polish Center for Technology Development, Stabłowicka 147, 54-066, Wrocław, Poland., Kubica-Bąk D; AGH UST, University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Mickiewicza 30, 30-059, Kraków, Poland. |
| Abstrakt: |
Fossil resins from Miocene coal deposit (Sarolangun mine, Jambi Province, Sumatra, Indonesia) have been analysed using spectroscopic methods: Raman Spectroscopy (RS), Fourier Transform-Infrared Spectroscopy (FT-IR), 13 C Nuclear Magnetic Resonance ( 13 C NMR), Fluorescence Spectroscopy (FS), and Gas Chromatography-Mass Spectrometry (GC-MS) in order to describe their diagnostic features. Simultaneously, glessite, a fossil resin from Upper Oligocene Bitterfeld deposit (Saxony-Anhalt, Germany), originating from similar botanical sources (i.e. angiosperms) was tested with the same analytical methods in order to find similarities and differences between the resins. The resins differ in colour, transparency and amounts of inclusions (resins from Sumatra-yellow, and transparent with few inclusions; glessite-brown-red, translucent with wealth of inclusions). In general, the IR and RS spectra of these resins are very similar, probably because the glessite colour-changing additives can be very subtle and non-observable in the infrared region. The RS spectra revealed also a slight difference in intensity ratio of the 1650/1450 cm -1 bands (0.56 and 0.68 for Sumatra and Germany resins, respectively), indicating a differences in their maturation process. The resins from Sumatra seem to be more mature than glessite from Germany. The excitation-emission (EM-EX) and synchronous spectra showed unique, chemical compositions of these resins, which are different one from another. The GC-MS data for Sumatran resins, dominated by sesquiterpenoids and triterpenoids (amyrin), confirmed their botanical origin (angiosperms as their biological affinities). The sesquiterpenoid biomarkers with cadine-structures suggested the glessite underwent more advanced polymerization processes, which does not correlate with its RS spectrum. The geological factors, the environmental conditions of resin deposition, and later various diagenesis processes may have influenced the maturation and crosslinking of compounds. Despite the genetic similarity of the resins from various part of the world, Sumatra and Germany, advanced techniques such as Gas Chromatography-Mass Spectrometry and Fluorescence Spectroscopy were the most useful to find the differences between them. These differences are predominantly a result of different diagenetic transformations of the resins. |
