Organic synthesis of high added value molecules with MOF catalysts.

Autor:	Martín N; Instituto de Ciencia Molecular (ICMol), Universitat de Valencia, Catedrático José Beltrán Martínez no 2, 46980 Paterna, Valencia, Spain. francisco.c.garcia@uv.es., Cirujano FG; Instituto de Ciencia Molecular (ICMol), Universitat de Valencia, Catedrático José Beltrán Martínez no 2, 46980 Paterna, Valencia, Spain. francisco.c.garcia@uv.es.
Jazyk:	angličtina
Zdroj:	Organic & biomolecular chemistry [Org Biomol Chem] 2020 Oct 21; Vol. 18 (40), pp. 8058-8073.
DOI:	10.1039/d0ob01571g
Abstrakt:	Recent examples of organic synthesis of fine chemicals and pharmaceuticals in confined spaces of MOFs are highlighted and compared with silica-based ordered porous solids, such as zeolites or mesoporous (organo)silica. These heterogeneous catalysts offer the possibility of stabilizing the desired transition states and/or intermediates during organic transformations of functional groups and (C-C/C-N) bond forming steps towards the desired functional high added value molecular scaffolds. A short introduction on zeolites, mesoporous silica and metal-organic frameworks is followed by relevant applications in which confined active sites in the pores promote single or multi-step organic synthesis of industrially relevant molecules. A critical discussion on the catalytic performances of the different types of hybrid inorganic-organic catalysts in the synthesis of O- and N-containing acyclic and heterocyclic molecules has been presented.
Databáze:	MEDLINE
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