| Autor: |
Cunningham DW; Department of Chemistry, University of California, Irvine, 92617, USA. j.yang@uci.edu., Yang JY; Department of Chemistry, University of California, Irvine, 92617, USA. j.yang@uci.edu. |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Oct 27; Vol. 56 (85), pp. 12965-12968. |
| DOI: |
10.1039/d0cc05556e |
| Abstrakt: |
[Pt(depe)2](PF6)2 electrocatalyzes the reversible conversion between CO2 and HCO2- with high selectivity and low overpotential but low rates. A comprehensive kinetic analysis indicates the rate determining step for CO2 reduction is the reactivity of a Pt hydride intermediate to produce HCO2-. To accelerate catalysis, the use of cationic and hydrogen-bond donor additives are explored. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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