Facile Synthesis and Synergetic Interaction of VPO/β-SiC Composites toward Solvent-Free Oxidation of Methanol to Formaldehyde.
| Autor: | Mishra G; Institute of Minerals and Materials Technology, CSIR, C&MC, Bhubaneswar 751013, Odisha, India., Behera GC; Department of Chemistry, M.P.C. Autonomous College, Takhatpur, Baripada 757003, Odisha, India., Singh SK; Advanced Materials Technology Department, CSIR-Institute of Minerals and Materials Technology, Bhubaneswar 751013, Odisha, India., Parida K; Centre for Nano Science & Nano Technology, SOA University, Bhubaneswar 751030, Odisha, India. |
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| Jazyk: | angličtina |
| Zdroj: | ACS omega [ACS Omega] 2020 Sep 01; Vol. 5 (36), pp. 22808-22815. Date of Electronic Publication: 2020 Sep 01 (Print Publication: 2020). |
| DOI: | 10.1021/acsomega.0c01921 |
| Abstrakt: | Composite materials have revealed remarkable activities in various catalytic applications. However, choosing an appropriate material to enhance the catalytic activity and stability is a major challenge in the field of catalysis. In this article, we reported vanadium phosphorus oxide (VPO)/β-SiC as a stable composite material with good catalytic activity. VPO/β-SiC composite materials with different compositions were fabricated by the impregnation technique to investigate the catalytic activity and stability of these materials in liquid-phase reactions. The physiochemical characteristics of the prepared catalysts were analyzed by several spectroscopic methods. The catalytic activities of VPO/β-SiC composites were studied in a solvent-free oxidation of methanol using tert -butyl hydroperoxide (TBHP) as an oxidant. The reaction conditions were optimized by changing various reaction parameters. Under optimized reaction conditions, the 10 wt % VPO/β-SiC composite showed 100% conversion with 89.8% selectivity to formaldehyde. Competing Interests: The authors declare no competing financial interest. (Copyright © 2020 American Chemical Society.) |
| Databáze: | MEDLINE |
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