Ba 3 (BO 3 )(CO 3 )F: The First Borate Carbonate Fluoride Synthesized by the High-Temperature Solution Method.

Autor: Huang C; CAS Key Laboratory of Functional Materials and Devices for Special, Environments, Xinjiang Technical Institute of Physics and Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, P. R. China.; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China., Zhang F; CAS Key Laboratory of Functional Materials and Devices for Special, Environments, Xinjiang Technical Institute of Physics and Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, P. R. China.; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China., Cheng S; CAS Key Laboratory of Functional Materials and Devices for Special, Environments, Xinjiang Technical Institute of Physics and Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, P. R. China., Yang Z; CAS Key Laboratory of Functional Materials and Devices for Special, Environments, Xinjiang Technical Institute of Physics and Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, P. R. China.; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China., Li H; CAS Key Laboratory of Functional Materials and Devices for Special, Environments, Xinjiang Technical Institute of Physics and Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, P. R. China.; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China., Pan S; CAS Key Laboratory of Functional Materials and Devices for Special, Environments, Xinjiang Technical Institute of Physics and Chemistry, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, P. R. China.; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2020 Dec 15; Vol. 26 (70), pp. 16628-16632. Date of Electronic Publication: 2020 Nov 16.
DOI: 10.1002/chem.202003606
Abstrakt: In contrast to the well-investigated halogen-containing borates and carbonates, very few halogen-containing borate carbonate compounds have been reported. Specifically, no example of borate carbonate fluoride has been synthesized successfully until now. Herein, the planar π-conjugated units [BO 3 ] 3- and [CO 3 ] 2- and the F - ions are introduced simultaneously into one crystal structure resulting in the first borate carbonate fluoride, Ba 3 (BO 3 )(CO 3 )F, by the high-temperature solution method in the atmosphere. Its structure features a hexagonal channel formed by the [BO 3 ] 3- and [CO 3 ] 2- units with the [F 3 Ba 8 ] 13+ trimers filled in the channel. Various characterizations including single crystal- and powder-XRD, EDX, IR, UV-vis-NIR, and TG-DSC, together with the first principles calculation have been carried out to verify the structure and fully understand the structure-property relationships.
(© 2020 Wiley-VCH GmbH.)
Databáze: MEDLINE
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