Molecular Vanadium Oxides for Energy Conversion and Energy Storage: Current Trends and Emerging Opportunities.

Autor: Anjass M; Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.; Helmholtz Institute Ulm, Helmholtzstrasse 12, 89081, Ulm, Germany., Lowe GA; Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany., Streb C; Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.; Helmholtz Institute Ulm, Helmholtzstrasse 12, 89081, Ulm, Germany.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2021 Mar 29; Vol. 60 (14), pp. 7522-7532. Date of Electronic Publication: 2020 Dec 17.
DOI: 10.1002/anie.202010577
Abstrakt: Molecular vanadium oxides, or polyoxovanadates (POVs), have recently emerged as a new class of molecular energy conversion/storage materials, which combine diverse, chemically tunable redox behavior and reversible multielectron storage capabilities. This Review explores current challenges, major breakthroughs, and future opportunities in the use of POVs for energy conversion and storage. The reactivity, advantages, and limitations of POVs are explored, with a focus on their use in lithium and post-lithium-ion batteries, redox-flow batteries, and light-driven energy conversion. Finally, emerging themes and new research directions are critically assessed to provide inspiration for how this promising materials class can advance research in sustainable energy technologies.
(© 2020 The Authors. Published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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