| Autor: |
Li AM; Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA. eichhorn@umd.edu., Wang Y, Zavalij PY, Chen F, Muñoz-Castro A, Eichhorn BW |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Sep 21; Vol. 56 (74), pp. 10859-10862. Date of Electronic Publication: 2020 Aug 13. |
| DOI: |
10.1039/d0cc03656k |
| Abstrakt: |
Cluster anions [Cp*RuPb 11 ] 3- (1) and [Cu@Cp*RuPb 11 ] 2- (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C 5v point symmetry and are static on the 207 Pb NMR time scale in solution. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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