A transition metal-gallium cluster formed via insertion of "GaI".

Autor: Blundell TJ; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Deborah.Kays@nottingham.ac.uk., Taylor LJ; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Deborah.Kays@nottingham.ac.uk., Valentine AJ; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Deborah.Kays@nottingham.ac.uk., Lewis W; The University of Sydney, F11 Eastern Ave, Sydney, NSW 2006, Australia., Blake AJ; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Deborah.Kays@nottingham.ac.uk., McMaster J; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Deborah.Kays@nottingham.ac.uk., Kays DL; School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Deborah.Kays@nottingham.ac.uk.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Jul 21; Vol. 56 (58), pp. 8139-8142.
DOI: 10.1039/d0cc03559a
Abstrakt: The reaction between a two-coordinate Co(ii) diaryl complex and "GaI" affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best described as a nido metalla-group 13 cluster.
Databáze: MEDLINE