Autor: |
Ilin EA; N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation., Smirnov VO, Volodin AD, Korlyukov AA, Dilman AD |
Jazyk: |
angličtina |
Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Jul 04; Vol. 56 (52), pp. 7140-7142. Date of Electronic Publication: 2020 May 28. |
DOI: |
10.1039/d0cc02567d |
Abstrakt: |
Compounds bearing ortho-oriented dialkylamino and boryl groups can serve as efficient reagents to trap difluorocarbene leading to zwitterionic ammonium borates featuring N-CF 2 -B fragments. The reagents are shelf-stable and can be used as mechanistic probes for reactions proceeding via difluorocarbene. |
Databáze: |
MEDLINE |
Externí odkaz: |
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