| Autor: |
Yuan H; Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore., Li N; Institute of Microelectronics, A*STAR (Agency for Science, Technology and Research), Fusionopolis Way, #08-02 Innovis Tower, 138634 Singapore., Linghu J; Department of Applied Physics, Chang'an University, Xi'an, Shaanxi 710064, China., Dong J; Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore., Wang Y; Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore., Karmakar A; Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore., Yuan J; Faculty of Science, Jiangsu University, Zhenjiang, Jiangsu 212013, China., Li M; Department of Materials Science and Engineering, National University of Singapore, 9 Engineering Drive 1, 117575 Singapore., Buenconsejo PJS; Facility for Analysis Characterisation Testing Simulation (FACTS), Nanyang Technological University, 50 Nanyang Avenue, 639798 Singapore., Liu G; Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore., Cai H; Institute of Microelectronics, A*STAR (Agency for Science, Technology and Research), Fusionopolis Way, #08-02 Innovis Tower, 138634 Singapore., Pennycook SJ; Department of Materials Science and Engineering, National University of Singapore, 9 Engineering Drive 1, 117575 Singapore., Singh N; Institute of Microelectronics, A*STAR (Agency for Science, Technology and Research), Fusionopolis Way, #08-02 Innovis Tower, 138634 Singapore., Zhao D; Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore. |
| Abstrakt: |
State-of-the-art chemical sensors based on covalent organic frameworks (COFs) are restricted to the transduction mechanism relying on luminescence quenching and/or enhancement. Herein, we present an alternative methodology via a combination of in situ-grown COF films with interdigitated electrodes utilized for capacitive benzene detection. The resultant COF-based sensors exhibit highly sensitive and selective detection at room temperature toward benzene vapor over carbon dioxide, methane, and propane. Their benzene detection limit can reach 340 ppb, slightly inferior to those of the metal oxide semiconductor-based sensors, but with reduced power consumption and increased selectivity. Such a sensing behavior can be attributed to the large dielectric constant of the benzene molecule, distinctive adsorptivity of the chosen COF toward benzene, and structural distortion induced by the custom-made interaction pair, which is corroborated by sorption measurements and density functional theory (DFT) calculations. This study provides new perspectives for fabricating COF-based sensors with specific functionality targeted for selective gas detection. |
