Shaping the Future of Fuel: Monolithic Metal-Organic Frameworks for High-Density Gas Storage.

Autor: Connolly BM; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom.; Adsorption & Advanced Materials Laboratory (A2ML), Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, United Kingdom., Madden DG; Adsorption & Advanced Materials Laboratory (A2ML), Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, United Kingdom., Wheatley AEH; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom., Fairen-Jimenez D; Adsorption & Advanced Materials Laboratory (A2ML), Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, United Kingdom.
Jazyk: angličtina
Zdroj: Journal of the American Chemical Society [J Am Chem Soc] 2020 May 13; Vol. 142 (19), pp. 8541-8549. Date of Electronic Publication: 2020 May 04.
DOI: 10.1021/jacs.0c00270
Abstrakt: The environmental benefits of cleaner, gaseous fuels such as natural gas and hydrogen are widely reported. Yet, practical usage of these fuels is inhibited by current gas storage technology. Here, we discuss the wide-ranging potential of gas-fuels to revolutionize the energy sector and introduce the limitations of current storage technology that prevent this transition from taking place. The practical capabilities of adsorptive gas storage using porous, crystalline metal-organic frameworks (MOFs) are examined with regard to recent benchmark results and ultimate storage targets in this field. In particular, the industrial limitations of typically powdered MOFs are discussed while recent breakthroughs in MOF processing are highlighted. We offer our perspective on the future of practical, rather than purely academic, MOF developments in the increasingly critical field of environmental fuel storage.
Databáze: MEDLINE