| Autor: |
Kilday MV, Johnson WH, Prosen EJ |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of research of the National Bureau of Standards. Section A, Physics and chemistry [J Res Natl Bur Stand A Phys Chem] 1961 Sep-Oct; Vol. 65A (5), pp. 435-440. Date of Electronic Publication: 1961 Oct 01. |
| DOI: |
10.6028/jres.065A.045 |
| Abstrakt: |
The heat of hydrolysis of dimethoxychloroborane has been measured; for the reaction, ( CH 3 O ) 2 BCl ( liq ) + 3 H 2 O ( liq ) = H 3 BO 3 ( c ) + 2 CH 3 OH ( liq ) + HCl ( g ) Δ H ( 25 ° C ) = - 26.6 ± 0.8 kj / mole = - 6.4 ± 0.2 kcal / mole . From this, we have calculated the heat of formation of dimethoxychloroborane: for the liquid, Δ Hf ° (25 °C) = -782.1 ± 1.8 kj/mole (-186.9±0.4 kcal/mole), and for the gas, Δ Hf ° (25 °C) = -747.9 ±2.2 kj/mole (-178.8±0.5 kcal/mole). |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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