| Autor: |
Alajarin M; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain., Ballester FJ; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain., Vivancos JA; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain., Orenes RA; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain., Vidal A; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain., Sanchez-Andrada P; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain., Marin-Luna M; Departamento de Quı́mica Orgánica, Facultad de Quı́mica, Regional Campus of International Excellence 'Campus Mare Nostrum', Universidad de Murcia, Murcia 30100, Spain. |
| Abstrakt: |
By virtue of its alkylidenecyclopropane moiety, 2-(cyclopropylidenemethyl)benzaldehyde reacts with a range of amines and thiols under Lewis acid catalysis. These reactions yield 1,3-bis(arylamino) and 1,3-bis(arylthio and alkylthio)indanes, respectively, which are spirolinked to the cyclopropane ring at carbon 2. The reaction mechanism, and the peculiar contribution of the cyclopropane ring, have been scrutinized via DFT calculations. |
