| Autor: |
Sol C; Photonic Innovations Laboratory, Department of Electronic & Electrical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K., Portnoi M; Photonic Innovations Laboratory, Department of Electronic & Electrical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K., Li T; Photonic Innovations Laboratory, Department of Electronic & Electrical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K., Gurunatha KL; Photonic Innovations Laboratory, Department of Electronic & Electrical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K., Schläfer J; Photonic Innovations Laboratory, Department of Electronic & Electrical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K., Guldin S; Department of Chemical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K., Parkin IP; Department of Chemistry , University College London , 20 Gordon Street , London WC1H 0AJ , U.K., Papakonstantinou I; Photonic Innovations Laboratory, Department of Electronic & Electrical Engineering , University College London , Torrington Place , London WC1E 7JE , U.K. |
| Abstrakt: |
Window coatings with dynamic solar transmittance represent an excellent opportunity to reduce building heating and cooling loads, which account for >40% of energy consumed by the built environment. In particular, inorganic vanadium dioxide-based thermochromic coatings offer long lifetimes (>30 years) and can be passively integrated into a window system without additional electronics or power requirements. However, their limited solar modulation depth and wide phase-change hysteresis have traditionally restricted their ability to adapt to changing weather conditions. Here, we derive an optical performance limit for thin film vanadium dioxide coatings, which we find to be far beyond the current literature. Furthermore, we experimentally demonstrate a solution-processed multilayer thin film coating that uses temperature-dependent optical impedance matching to approach the optical performance limit. The thin film coating demonstrated has a record solar transmittance modulation of 21.8% while maintaining a high level of visible transparency (∼50%) and minimal hysteresis (∼10 °C). This work represents a step-change in thin film thermochromic window coatings and, as a result, establishes planar thin film vanadium dioxide as the most viable morphology for high-performance thermochromic windows. |
