Dissociative recombination of N 2 H + ions with electrons in the temperature range of 80-350 K.

Autor: Shapko D; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Dohnal P; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Kassayová M; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Kálosi Á; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Rednyk S; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Roučka Š; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Plašil R; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic., Augustovičová LD; Faculty of Mathematics and Physics, Department of Chemical Physics and Optics, Charles University, Prague, Czech Republic., Johnsen R; Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA., Špirko V; Faculty of Mathematics and Physics, Department of Chemical Physics and Optics, Charles University, Prague, Czech Republic., Glosík J; Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, Prague, Czech Republic.
Jazyk: angličtina
Zdroj: The Journal of chemical physics [J Chem Phys] 2020 Jan 14; Vol. 152 (2), pp. 024301.
DOI: 10.1063/1.5128330
Abstrakt: Recombination of N 2 H + ions with electrons was studied using a stationary afterglow with a cavity ring-down spectrometer. We probed in situ the time evolutions of number densities of different rotational and vibrational states of recombining N 2 H + ions and determined the thermal recombination rate coefficients for N 2 H + in the temperature range of 80-350 K. The newly calculated vibrational transition moments of N 2 H + are used to explain the different values of recombination rate coefficients obtained in some of the previous studies. No statistically significant dependence of the measured recombination rate coefficient on the buffer gas number density was observed.
Databáze: MEDLINE
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