| Autor: |
Puskarevsky NA; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia. nikolay@niic.nsc.ru., Smolentsev AI, Dmitriev AA, Vargas-Baca I, Gritsan NP, Beckmann J, Zibarev AV |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Jan 23; Vol. 56 (7), pp. 1113-1116. |
| DOI: |
10.1039/c9cc08110k |
| Abstrakt: |
Reduction of 2,1,3-benzotelluradiazole (3) yielded a crystalline solid that features a trimeric dianion formally composed of two [3]˙- and one 3 bridged by unusually asymmetric TeN chalcogen bonds. The solid is diamagnetic due to strong antiferromagnetic coupling, as revealed by CASSCF/CASPT2 and BS-DFT. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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