The chemical and chemo-ecological studies on Weizhou nudibranch Glossodoris atromarginata.
Autor: | Li XL; Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Leibniz-Forschungsinstitut für Molekulare Pharmakologie (FMP), Berlin, Germany., Li SW; State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai, China., Yao LG; State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai, China., Mollo E; Consiglio Nazionaledelle Ricerche (CNR), Istituto di Chimica Biomolecolare (ICB), Pozzuoli, Italy., Gavagnin M; Consiglio Nazionaledelle Ricerche (CNR), Istituto di Chimica Biomolecolare (ICB), Pozzuoli, Italy., Guo YW; State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai, China. |
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Jazyk: | angličtina |
Zdroj: | Magnetic resonance in chemistry : MRC [Magn Reson Chem] 2021 May; Vol. 59 (5), pp. 554-560. Date of Electronic Publication: 2019 Nov 15. |
DOI: | 10.1002/mrc.4949 |
Abstrakt: | A detailed chemical investigation of the nudibranch Glossodoris atromarginata collected from Weizhou Island, South China Sea, yielded a new spongian-type diterpene 1, together with the four known-related compounds 2-5. The structure of the new compound 1 was elucidated by the detailed spectroscopic analysis, the comparison of the spectroscopic data with the known diterpene isoagatholactone, and the 13 C chemical shift calculation. In addition, evidence for the absolute stereochemistry of the known compound 2 was, for the first time, provided by the application of time-dependent density functional theory electronic circular dichroism calculation. (© 2019 John Wiley & Sons, Ltd.) |
Databáze: | MEDLINE |
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