The crystal structure of ((cyclo-hexyl-amino){( Z )-2-[( E )-5-meth-oxy-3-nitro-2-oxido-benzyl-idene-κ O ]hydrazin-1-yl-idene-κ N 2 }methane-thiol-ato-κ S )(dimethyl sulfoxide-κ S )platinum(II): a supra-molecular two-dimensional network.

Autor: Arafath MA; Department of Chemistry, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh., Kwong HC; School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, Malaysia., Adam F; School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, Malaysia.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2019 Sep 12; Vol. 75 (Pt 10), pp. 1486-1489. Date of Electronic Publication: 2019 Sep 12 (Print Publication: 2019).
DOI: 10.1107/S2056989019012623
Abstrakt: The Pt II atom in the title complex, [Pt(C 15 H 18 N 4 O 4 S)(C 2 H 6 OS)], exists within a square-planar NS 2 O donor set provided by the N, S, O atoms of the di-anionic tridentate thio-semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S-Pt-S bite angle of 96.45 (2)°. In the crystal, mol-ecules are linked via N-H⋯O, C-H⋯O, C-H⋯N and C-H⋯π inter-actions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclo-hexyl-hydrazine-1-carbo-thio-amide ligands are compared to that of the title compound.
(© Arafath et al. 2019.)
Databáze: MEDLINE
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