NpSe 2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal.

Autor: Jin GB; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA.; Current address: 3M Corporate Research Analytical Laboratory, St. Paul, MN, 55144, USA., Malliakas CD; Material Science Division, Argonne National Laboratory, Argonne, IL, 60439, USA.; Current address: Northwestern University, Evanston, IL, USA., Hu YJ; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA., Booth CH; Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA., Ibers JA; Department of Chemistry, Northwestern University, Evanston, IL, 60208-3113, USA., Sokaras D; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California, 94025, USA., Weng TC; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California, 94025, USA.; Current address: HPSTAR, 1690 Cailun Rd., Bldg. 6, Shanghai, 201203, China., Skanthakumar S; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA., Soderholm L; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2019 Nov 04; Vol. 58 (45), pp. 16130-16133. Date of Electronic Publication: 2019 Sep 24.
DOI: 10.1002/anie.201910353
Abstrakt: A new binary compound, NpSe 2, possesses metal-chalcogen and chalcogen-chalcogen interactions different from those reported for other metal dichalcogenides. Its structure is incommensurately modulated and features linear Se chains and valence-ambiguous Np cations.
(© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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