Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates.
| Autor: | Reddy CR; Centre for Semiochemicals and Laboratory of X-ray Crystallography, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India., Sridhar B; Centre for Semiochemicals and Laboratory of X-ray Crystallography, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India., V Subba Reddy B; Centre for Semiochemicals and Laboratory of X-ray Crystallography, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India. |
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| Jazyk: | angličtina |
| Zdroj: | ACS omega [ACS Omega] 2018 Aug 22; Vol. 3 (8), pp. 9746-9753. Date of Electronic Publication: 2018 Aug 22 (Print Publication: 2018). |
| DOI: | 10.1021/acsomega.8b01118 |
| Abstrakt: | A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C-C and C-N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner. Competing Interests: The authors declare no competing financial interest. |
| Databáze: | MEDLINE |
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