The Effect of Acceptor Structure on Emission Color Tuning in Organic Semiconductors with D-π-A-π-D Structures.

Autor: Ledwon P; Faculty of Chemistry, Silesian University of Technology, Strzody 9, 44-100 Gliwice, Poland. przemyslaw.ledwon@polsl.pl., Wiosna-Salyga G; Department of Molecular Physics, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland. gabriela.wiosna-salyga@p.lodz.pl., Chapran M; Department of Molecular Physics, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland., Motyka R; Faculty of Chemistry, Silesian University of Technology, Strzody 9, 44-100 Gliwice, Poland.
Jazyk: angličtina
Zdroj: Nanomaterials (Basel, Switzerland) [Nanomaterials (Basel)] 2019 Aug 17; Vol. 9 (8). Date of Electronic Publication: 2019 Aug 17.
DOI: 10.3390/nano9081179
Abstrakt: A series of novel donor-acceptor D-π-A-π-D compounds were synthesized and characterized in order to determine the influence of different acceptor units on their properties. The introduction of acceptor moieties had a direct impact on the HOMO and LUMO energy levels. Fluorescence spectra of compounds can be changed by the choice of an appropriate acceptor and were shifted from the green to the near-infrared part of spectra. Due to observed concentration induced emission quenching, the green exciplex type host was used to evaluate the potential of synthesized molecules as emitters in organic light emitting diodes (OLEDs).
Databáze: MEDLINE