Regional Discrimination of Australian Shiraz Wine Volatome by Two-Dimensional Gas Chromatography Coupled to Time-of-Flight Mass Spectrometry.

Autor: Šuklje K, Carlin S; Department of Food Quality and Nutrition , Fondazione Edmund Mach, Research and Innovation Centre , San Michele all'Adige 38010 , Trentino , Italy., Antalick G, Blackman JW, Deloire A, Vrhovsek U; Department of Food Quality and Nutrition , Fondazione Edmund Mach, Research and Innovation Centre , San Michele all'Adige 38010 , Trentino , Italy., Schmidtke LM
Jazyk: angličtina
Zdroj: Journal of agricultural and food chemistry [J Agric Food Chem] 2019 Sep 11; Vol. 67 (36), pp. 10273-10284. Date of Electronic Publication: 2019 Aug 29.
DOI: 10.1021/acs.jafc.9b03563
Abstrakt: Shiraz wine volatomes from two Australian geographical indications (GIs), that is, Orange and Riverina, were compared using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry. Shiraz wines were made in triplicate from grapes harvested at two harvest dates from six vineyards in the two GIs. A total of 133 compounds showed a significant trend between wines from the cooler Orange GI and warmer Riverina. Compounds associated with wines from the cooler climate were grape-derived volatiles, such as monoterpenes, sesquiterpenes, green leaf volatiles, and some norisoprenoids. Fermentation-derived compounds, such as esters and S-containing compounds, showed no specific trend related to grape origin. In addition, wines could be also clearly separated according to the harvest date, irrespective of the climate, with C6 compounds, higher alcohol acetates, and other esters contributing utmost to the differentiation of samples, whereas terpenoids and norisoprenoids did not have an influence. This study demonstrated the plasticity of wine volatome related to grape origin and also the maturity level (harvest date), irrespective of climate.
Databáze: MEDLINE