Crystal structure of N -(di-phenyl-phosphor-yl)-2-meth-oxy-benzamide.

Autor:	Trush VA; Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska, str. 64, 01601 Kyiv, Ukraine., Kariaka NS; Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska, str. 64, 01601 Kyiv, Ukraine., Dyakonenko VV; SSI 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Nauki Ave 60, Kharkiv 61001, Ukraine., Shishkina SV; SSI 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Nauki Ave 60, Kharkiv 61001, Ukraine., Amirkhanov VM; Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska, str. 64, 01601 Kyiv, Ukraine.
Jazyk:	angličtina
Zdroj:	Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2019 Jun 04; Vol. 75 (Pt 7), pp. 939-941. Date of Electronic Publication: 2019 Jun 04 (Print Publication: 2019).
DOI:	10.1107/S205698901900762X
Abstrakt:	In the title compound, C 20 H 18 NO 3 P, the C=O and P=O groups of the carbacyl-amido-phosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N-H group is involved in the formation of an intra-molecular hydrogen bond. In the crystal, mol-ecules do not form strong inter-molecular inter-actions but the mol-ecules are linked via weak C-H⋯π inter-actions, forming chains along [001].
Databáze:	MEDLINE
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