Revealing the Simultaneous Effects of Conductivity and Amorphous Nature of Atomic-Layer-Deposited Double-Anion-Based Zinc Oxysulfide as Superior Anodes in Na-Ion Batteries.

Autor: Sinha S; Department of Materials Science and Engineering and Optoelectronics Convergence Research Center, Chonnam National University, Gwangju, 61186, Republic of Korea., Didwal PN; Department of Materials Science and Engineering and Optoelectronics Convergence Research Center, Chonnam National University, Gwangju, 61186, Republic of Korea., Nandi DK; School of Materials Science and Engineering, Yeungnam University, 214-1, Dae-dong, Gyeongsan-si, 38541, Republic of Korea., Verma R; Department of Materials Science and Engineering and Optoelectronics Convergence Research Center, Chonnam National University, Gwangju, 61186, Republic of Korea., Cho JY; Department of Materials Science and Engineering and Optoelectronics Convergence Research Center, Chonnam National University, Gwangju, 61186, Republic of Korea., Kim SH; School of Materials Science and Engineering, Yeungnam University, 214-1, Dae-dong, Gyeongsan-si, 38541, Republic of Korea., Park CJ; Department of Materials Science and Engineering and Optoelectronics Convergence Research Center, Chonnam National University, Gwangju, 61186, Republic of Korea., Heo J; Department of Materials Science and Engineering and Optoelectronics Convergence Research Center, Chonnam National University, Gwangju, 61186, Republic of Korea.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2019 Sep; Vol. 15 (37), pp. e1900595. Date of Electronic Publication: 2019 Aug 02.
DOI: 10.1002/smll.201900595
Abstrakt: Although sodium-ion batteries (SIBs) are considered promising alternatives to their Li counterparts, they still suffer from challenges like slow kinetics of the sodiation process, large volume change, and inferior cycling stability. On the other hand, the presence of additional reversible conversion reactions makes the metal compounds the preferred anode materials over carbon. However, conductivity and crystallinity of such materials often play the pivotal role in this regard. To address these issues, atomic layer deposited double-anion-based ternary zinc oxysulfide (ZnOS) thin films as an anode material in SIBs are reported. Electrochemical studies are carried out with different O/(O+S) ratios, including O-rich and S-rich crystalline ZnOS along with the amorphous phase. Amorphous ZnOS with the O/(O+S) ratio of ≈0.4 delivers the most stable and considerably high specific (and volumetric) capacities of 271.9 (≈1315.6 mAh cm -3 ) and 173.1 mAh g -1 (≈837.7 mAh cm -3 ) at the current densities of 500 and 1000 mA g -1 , respectively. A dominant capacitive-controlled contribution of the amorphous ZnOS anode indicates faster electrochemical reaction kinetics. An electrochemical reaction mechanism is also proposed via X-ray photoelectron spectroscopy analyses. A comparison of the cycling stability further establishes the advantage of this double-anion-based material over pristine ZnO and ZnS anodes.
(© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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