Design and synthesis of capped-paddlewheel-based porous coordination cages.

Autor: Lorzing GR; Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. edb@udel.edu and Center for Neutron Science, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, USA., Gosselin AJ; Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. edb@udel.edu., Lindner BS; Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. edb@udel.edu., Bhattacharjee R; Catalysis Center for Energy Innovation (CCEI) University of Delaware, Newark, Delaware 19716, USA., Yap GPA; Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. edb@udel.edu., Caratzoulas S; Catalysis Center for Energy Innovation (CCEI) University of Delaware, Newark, Delaware 19716, USA., Bloch ED; Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. edb@udel.edu and Center for Neutron Science, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, USA and Catalysis Center for Energy Innovation (CCEI) University of Delaware, Newark, Delaware 19716, USA.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Aug 07; Vol. 55 (64), pp. 9527-9530.
DOI: 10.1039/c9cc05002g
Abstrakt: To leverage the structural diversity of metal-organic frameworks, the ability to controllably terminate them for the isolation of porous coordination cages is advantageous. However, the strategy has largely been limited to ligand termination methods, particularly for paddlewheel-based materials. Here, we show a paddlewheel-capping strategy can be employed to afford previously unattainable coordination cage structures that are mimetic of metal-organic framework pores.
Databáze: MEDLINE