| Autor: |
Lorzing GR, Gosselin AJ, Trump BA; Center for Neutron Research , National Institute of Standards and Technology , Gaithersburg , Maryland 20899 , United States., York AHP; School of Chemical, Biological, and Environmental Engineering , Oregon State University , Corvallis , Oregon 97331 , United States., Sturluson A; School of Chemical, Biological, and Environmental Engineering , Oregon State University , Corvallis , Oregon 97331 , United States., Rowland CA, Yap GPA, Brown CM; Center for Neutron Research , National Institute of Standards and Technology , Gaithersburg , Maryland 20899 , United States., Simon CM; School of Chemical, Biological, and Environmental Engineering , Oregon State University , Corvallis , Oregon 97331 , United States., Bloch ED |
| Abstrakt: |
Porous molecular solids are promising materials for gas storage and gas separation applications. However, given the relative dearth of structural information concerning these materials, additional studies are vital for further understanding their properties and developing design parameters for their optimization. Here, we examine a series of isostructural cuboctahedral, paddlewheel-based coordination cages, M 24 ( t Bu-bdc) 24 (M = Cr, Mo, Ru; t Bu-bdc 2- = 5- tert -butylisophthalate), for high-pressure methane storage. As the decrease in crystallinity upon activation of these porous molecular materials precludes diffraction studies, we turn to a related class of pillared coordination cage-based metal-organic frameworks, M 24 (Me-bdc) 24 (dabco) 6 (M = Fe, Co; Me-bdc 2- = 5-methylisophthalate; dabco = 1,4-diazabicyclo[2.2.2]octane) for neutron diffraction studies. The five porous materials display BET surface areas from 1057-1937 m 2 /g and total methane uptake capacities of up to 143 cm 3 (STP)/cm 3 . Both the porous cages and cage-based frameworks display methane adsorption enthalpies of -15 to -22 kJ/mol. Also supported by molecular modeling, neutron diffraction studies indicate that the triangular windows of the cage are favorable methane adsorption sites with CD 4 -arene interactions between 3.7 and 4.1 Å. At both low and high loadings, two additional methane adsorption sites on the exterior surface of the cage are apparent for a total of 56 adsorption sites per cage. These results show that M 24 L 24 cages are competent gas storage materials and further adsorption sites may be optimized by judicious ligand functionalization to control extracage pore space. |
