In-situ Chemiluminescence-Driven Reversible Addition-Fragmentation Chain-Transfer Photopolymerization.

Autor: De Alwis Watuthanthrige N; Department of Chemistry and Biochemistry, Miami University, 651 E High Street, Oxford, OH, 45011, USA., Allegrezza ML; Department of Chemistry and Biochemistry, Miami University, 651 E High Street, Oxford, OH, 45011, USA., Dolan MT; Department of Chemistry and Biochemistry, Miami University, 651 E High Street, Oxford, OH, 45011, USA., Kloster AJ; Department of Chemistry and Biochemistry, Miami University, 651 E High Street, Oxford, OH, 45011, USA., Kovaliov M; Neuroscience Institute, Allegheny Health Network, 320 East North Ave, Pittsburgh, PA, 15212, USA., Averick S; Neuroscience Institute, Allegheny Health Network, 320 East North Ave, Pittsburgh, PA, 15212, USA., Konkolewicz D; Department of Chemistry and Biochemistry, Miami University, 651 E High Street, Oxford, OH, 45011, USA.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2019 Aug 19; Vol. 58 (34), pp. 11826-11829. Date of Electronic Publication: 2019 Jul 25.
DOI: 10.1002/anie.201905317
Abstrakt: The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.
(© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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