| Autor: |
Baglai I; AMOLF, Science Park 104, 1098 XG Amsterdam, The Netherlands. noorduin@amolf.nl., Leeman M, Kaptein B, Kellogg RM, Noorduin WL |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Jun 11; Vol. 55 (48), pp. 6910-6913. |
| DOI: |
10.1039/c9cc03250a |
| Abstrakt: |
Herein we introduce a "chiral switch" - a sequence of operations that alternate between equilibrium and non-equilibrium conditions to switch the absolute configuration of a chiral center. The generality and practical potential of the technique are demonstrated with three unnatural α-amino acid precursors. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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