( E )-2-(2-Hy-droxy-3-methyl-benzyl-idene)- N -methyl-hydrazine-1-carbo-thio-amide: supra-molecular assemblies in two-dimensions mediated by N-H⋯S and C-H⋯π inter-actions.

Autor: Arafath MA; Department of Chemistry, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh., Kwong HC; School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, Malaysia., Adam F; School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, Malaysia.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2019 Apr 05; Vol. 75 (Pt 5), pp. 571-575. Date of Electronic Publication: 2019 Apr 05 (Print Publication: 2019).
DOI: 10.1107/S2056989019004444
Abstrakt: In the title compound, C 10 H 13 N 3 OS, the azomethine C=N double bond has an E configuration. The phenyl ring and methyl-hydrazine carbo-thio-amide moiety [maximum deviation = 0.008 (2) Å] are twisted slightly with a dihedral angle of 14.88 (10)°. In the crystal, mol-ecules are linked into sheets parallel to the ab plane via N-H⋯S hydrogen bonds and C-H⋯π inter-actions.
Databáze: MEDLINE