Morphologies Transformation of BODIPY-Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets.

Autor: Zhou LL; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China., Chen JY; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China., Li XY; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China., Li H; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China., Wang H; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China., Wang DG; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China., Kuang GC; State Key Laboratory of Power Metallurgy, Central South University, Lushan South Road 932, Yuelu District Changsha, Hunan, 410083, P. R. China.
Jazyk: angličtina
Zdroj: Macromolecular rapid communications [Macromol Rapid Commun] 2019 Aug; Vol. 40 (15), pp. e1900182. Date of Electronic Publication: 2019 May 14.
DOI: 10.1002/marc.201900182
Abstrakt: The aggregate morphologies of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) main chain supramolecular polymer amphiphiles (SPA) are tunable by a fine balance of different non-covalent interactions. When the BODIPY segments and sodium cholate are mixed in aqueous solution, they form SPA by electrostatic attraction and hydrogen-bonds. This SPA displays helical nanowires' morphology. After the third component dimeric β-cyclodextrin (β-CD-C) is added, the hydrogen bonds between the cholate are substituted by the host-guest interaction between cholate and β-CD-C. Therefore, these SPA transform their aggregate morphologies into nanosheets' architecture. Therefore, a simple and effective way to regulate self-assembly by non-covalent forces is developed. This supramolecular method may provide an effective way to prepare various nanostructures in aqueous solution and show promising application in the future.
(© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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