Quantitative in situ 13 C NMR studies of the electro-catalytic oxidation of ethanol.
| Autor: | Richter JB; Chair of Bioanalytical Chemistry, TU Dresden, Bergstraße 66, 01069 Dresden, Germany. eike.brunner@tu-dresden.de., Eßbach C; Chair of Inorganic Chemistry I, TU Dresden, Bergstraße 66, 01069 Dresden, Germany., Senkovska I; Chair of Inorganic Chemistry I, TU Dresden, Bergstraße 66, 01069 Dresden, Germany., Kaskel S; Chair of Inorganic Chemistry I, TU Dresden, Bergstraße 66, 01069 Dresden, Germany., Brunner E; Chair of Bioanalytical Chemistry, TU Dresden, Bergstraße 66, 01069 Dresden, Germany. eike.brunner@tu-dresden.de. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 May 28; Vol. 55 (43), pp. 6042-6045. Date of Electronic Publication: 2019 May 08. |
| DOI: | 10.1039/c9cc02660f |
| Abstrakt: | The identification and quantification of reaction intermediates and products in a time-resolved fashion is of great value for the understanding of mechanisms underlying the electro-catalytic oxidation of alcohols. Using a newly developed in situ cell, the identification of different intermediates, products, and side products became possible by monitoring the ethanol electro-oxidation in operando by 13 C NMR spectroscopy. |
| Databáze: | MEDLINE |
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