| Autor: |
Tuffnell JM; Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, CB3 0FS, UK. Tdb35@cam.ac.uk., Ashling CW, Hou J, Li S, Longley L, Ríos Gómez ML, Bennett TD |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Jul 23; Vol. 55 (60), pp. 8705-8715. |
| DOI: |
10.1039/c9cc01468c |
| Abstrakt: |
Metal-organic frameworks (MOFs) are often, and incorrectly, believed to be purely crystalline solids. This Feature Article highlights a selection of highly disordered MOF-based materials. This disorder gives rise to numerous possibilities in the fabrication of new MOF materials, and presents an alternative method of novel materials discovery, outside of the synthesis of increasingly complex crystalline structures. The formation of liquid MOFs and resultant melt-quenched glasses is reviewed, along with several categories of novel MOF-based materials including blends, flux melted glasses and crystal-glass composites. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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