Connecting Wires: Photoinduced Electronic Structure Modulation in Metal-Organic Frameworks.

Autor: Dolgopolova EA; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Galitskiy VA; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Martin CR; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Gregory HN; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Yarbrough BJ; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Rice AM; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Berseneva AA; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Ejegbavwo OA; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Stephenson KS; Department of Physics and Astronomy , University of South Carolina , Columbia , South Carolina 29208 , United States., Kittikhunnatham P; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Karakalos SG; College of Engineering and Computing , University of South Carolina , Columbia , South Carolina 29208 , United States., Smith MD; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Greytak AB; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Garashchuk S; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States., Shustova NB; Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States.
Jazyk: angličtina
Zdroj: Journal of the American Chemical Society [J Am Chem Soc] 2019 Apr 03; Vol. 141 (13), pp. 5350-5358. Date of Electronic Publication: 2019 Mar 18.
DOI: 10.1021/jacs.8b13853
Abstrakt: Electronic structure modulation of metal-organic frameworks (MOFs) through the connection of linker "wires" as a function of an external stimulus is reported for the first time. The established correlation between MOF electronic properties and photoisomerization kinetics as well as changes in an absorption profile is unprecedented for extended well-defined structures containing coordinatively integrated photoresponsive linkers. The presented studies were carried out on both single crystal and bulk powder with preservation of framework integrity. An LED-containing electric circuit, in which the switching behavior was driven by the changes in MOF electronic profile, was built for visualization of experimental findings. The demonstrated concept could be used as a blueprint for development of stimuli-responsive materials with dynamically controlled electronic behavior.
Databáze: MEDLINE
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