Autor: |
Zhang J; State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China., Longley L, Liu H, Ashling CW, Chater PA, Beyer KA, Chapman KW, Tao H, Keen DA, Bennett TD, Yue Y |
Jazyk: |
angličtina |
Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Feb 21; Vol. 55 (17), pp. 2521-2524. |
DOI: |
10.1039/c8cc09574d |
Abstrakt: |
A pronounced enthalpy release occurs around 1.38Tg in the prototypical metal-organic framework glass formed from ZIF-4 [Zn(C3H3N2)2], but there is no sign for any crystallization (i.e., long-range ordering) taking place. The enthalpy release peak is attributed to pore collapse and structural densification. |
Databáze: |
MEDLINE |
Externí odkaz: |
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