Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks.

Autor: Bhattacharya S; Department of Life Sciences and Chemistry , Jacobs University , Campus Ring 1 , 28759 Bremen , Germany., Ayass WW; Department of Life Sciences and Chemistry , Jacobs University , Campus Ring 1 , 28759 Bremen , Germany., Taffa DH; Institute of Chemistry , Carl von Ossietzky University Oldenburg , 26129 Oldenburg , Germany., Schneemann A; Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching , Germany., Semrau AL; Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching , Germany., Wannapaiboon S; Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching , Germany., Altmann PJ; Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching , Germany., Pöthig A; Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching , Germany., Nisar T; Department of Physics and Earth Sciences , Jacobs University , Campus Ring 1 , 28759 Bremen , Germany., Balster T; Department of Physics and Earth Sciences , Jacobs University , Campus Ring 1 , 28759 Bremen , Germany., Burtch NC; Sandia National Laboratories , Livermore , California 94551 , United States., Wagner V; Department of Physics and Earth Sciences , Jacobs University , Campus Ring 1 , 28759 Bremen , Germany., Fischer RA; Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching , Germany., Wark M; Institute of Chemistry , Carl von Ossietzky University Oldenburg , 26129 Oldenburg , Germany., Kortz U; Department of Life Sciences and Chemistry , Jacobs University , Campus Ring 1 , 28759 Bremen , Germany.
Jazyk: angličtina
Zdroj: Journal of the American Chemical Society [J Am Chem Soc] 2019 Feb 27; Vol. 141 (8), pp. 3385-3389. Date of Electronic Publication: 2019 Feb 15.
DOI: 10.1021/jacs.8b13397
Abstrakt: Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd 13 O 8 (AsO 4 ) 8 H 6 ] 8- decorated by four Ba 2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.
Databáze: MEDLINE
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