| Autor: |
Bin Ismail ML; Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore. CWSo@ntu.edu.sg., So CW |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Feb 12; Vol. 55 (14), pp. 2074-2077. |
| DOI: |
10.1039/c8cc09454c |
| Abstrakt: |
The synthesis of a dimeric phosphine-stabilized phosphidogermanium(i)-amidogermanium(ii) derivative is described. The reaction of amidinato phosphinoamidosilylene [L{(Ar)(Ph2P)N}Si:] (1, L = PhC(NtBu)2, Ar = 2,6-iPr2C6H3) with GeCl2·dioxane afforded a phosphine-stabilized phosphidogermanium(i) dimer moiety in a mixed-valent germanium(i,ii) compound [:Ge(Cl){N(Ar)PPh2}(Ph2P)Ge:]2 (3). The mechanism for the formation of 3 is also studied and reported. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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