| Autor: |
Deak N; Universitatea Babes-Bolyai, Facultatea de Chimie si Inginerie Chimica, Departamentul de Chimie, str. Kogalniceanu, nr; 1, RO-400084, Cluj-Napoca, Romania. gabriela.nemes@ubbcluj.ro., Thillaye du Boullay O, Moraru IT, Mallet-Ladeira S, Madec D, Nemes G |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2019 Feb 12; Vol. 48 (7), pp. 2399-2406. |
| DOI: |
10.1039/c8dt05116j |
| Abstrakt: |
New chiral heteroleptic germanium(ii) and tin(ii) metallylenes were obtained using 1-(para-tolylsulfinyl)-3-tosyl-5-tert-butyl-benzene as a non-symmetric O,C,O-chelating pincer ligand. Crystallographic analysis and DFT calculations indicate that the non-symmetric sulfinyl-sulfonyl pincer ligand acts as an O,C,O-coordinating pincer-type-ligand with predominant sulfinyl intramolecular S[double bond, length as m-dash]O coordination to germanium(ii) and tin(ii) centers. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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