Modulation of emission properties of phosphine-sulfonate ligand containing copper complexes: playing with solvato-, thermo-, and mechanochromism.

Autor: Vacher A; Univ Rennes, Institut des Sciences Chimiques de Rennes-UMR 6226, ScanMat-UMS2001, F-35000 Rennes, France. abdou.boucekkine@univ-rennes1.fr huriye.akdas@univ-rennes1.fr mathieu.achard@univ-rennes1.fr., Amar A, Camerel F, Molard Y, Latouche C, Roisnel T, Dorcet V, Boucekkine A, Akdas-Kiliç H, Achard M
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2019 Feb 05; Vol. 48 (6), pp. 2128-2134.
DOI: 10.1039/c8dt04502j
Abstrakt: Modulations of various neutral phosphine containing copper(i) complexes exhibiting phosphorescence and TADF are easily achieved by solvent modification restricting intramolecular rotation or by modifying the L-X phosphine-sulfonate chelate. This concept is not limited to solvents as the addition of metallic salts also led to the formation of original well-defined photoluminescent K2CuLX3 and KCuL2X2 cuprate complexes.
Databáze: MEDLINE