Sonochemical Degradation of Benzothiophene (BT) in Deionized Water, Natural Water and Sea Water.

Autor: Al-Zaydi KM; Department of Chemistry, Sciences Faculty -AL Faisaliah, King Abdulaziz University, Jeddah, P.O. Box 50918, Jeddah 21533, Saudi Arabia. kalzaydi@kau.edu.sa.; Chemistry Department, Faculty of Science, University of Jeddah, P.O. Box 80327, Jeddah 21589, Saudi Arabia. kalzaydi@kau.edu.sa., Petrier C; Department of Chemistry, Sciences Faculty -AL Faisaliah, King Abdulaziz University, Jeddah, P.O. Box 50918, Jeddah 21533, Saudi Arabia. Christian.Petrier@univ-savoie.fr.; Rheology and processes Laboratory UMR 5520- UJF-Grenoble INP-CNR, Laboratoire Rhéologie et Procédés, Domaine Universitaire, 38041 Grenoble, France. Christian.Petrier@univ-savoie.fr., Mousally SMM; Department of Chemistry, Sciences Faculty -AL Faisaliah, King Abdulaziz University, Jeddah, P.O. Box 50918, Jeddah 21533, Saudi Arabia. smousally@kau.edu.sa.; Chemistry Department, Faculty of Science, University of Jeddah, P.O. Box 80327, Jeddah 21589, Saudi Arabia. smousally@kau.edu.sa., Arab ST; Department of Chemistry, Sciences Faculty -AL Faisaliah, King Abdulaziz University, Jeddah, P.O. Box 50918, Jeddah 21533, Saudi Arabia. dr.s.arab@hotmail.com.; Chemistry Department, Faculty of Science, University of Jeddah, P.O. Box 80327, Jeddah 21589, Saudi Arabia. dr.s.arab@hotmail.com., Refat MS; Chemistry Department, Faculty of Science, Taif University, P.O. Box 888, Al-Hawiah, Taif 21974, Saudi Arabia. msrefat@yahoo.com.; Department of Chemistry, Faculty of Science, Port Said, Port Said University, Port Said 42526, Egypt. msrefat@yahoo.com.
Jazyk: angličtina
Zdroj: Molecules (Basel, Switzerland) [Molecules] 2019 Jan 11; Vol. 24 (2). Date of Electronic Publication: 2019 Jan 11.
DOI: 10.3390/molecules24020257
Abstrakt: This paper deals with the sonochemical water treatment of polycyclic aromatic sulfur hydrocarbons (PASHs), one of the most common impurities found in waste water coming from petroleum industry. The best fit of the experimental data appears to be the kinetic parameters determined using the Michaelis-Mentonmodel in the concentrations range of the study. For the initial increase in the degradation rates, it is simply considered that the more the bulk concentration increases, the more the concentration in the interfacial region increases. This will be explained by Michaelis-Menton kinetics. The influence of organic compounds in the water matrix as a mixture with Benzothiophene (BT) was also evaluated. The results indicated that BT degradation is unaffected by the presence of bisphenol A (BPA). Finally, the results indicated that ultrasonic action is involved in oxidation rather than pyrolitic processing in the BT sonochemical degradation.
Databáze: MEDLINE
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