| Autor: |
Tamang SR; Department of Chemistry & Biochemistry, Texas Tech University, Lubbock, TX 79409, USA. michael.findlater@ttu.edu., Cozzolino AF, Findlater M |
| Jazyk: |
angličtina |
| Zdroj: |
Organic & biomolecular chemistry [Org Biomol Chem] 2019 Feb 13; Vol. 17 (7), pp. 1834-1838. |
| DOI: |
10.1039/c8ob02661k |
| Abstrakt: |
The reaction of (dppBIAN)FeCl2 with 3 equivalents of n-BuLi affords a catalytically active anionic Fe complex; the nature of the anionic complex was probed using EPR and IR experiments and is proposed to involve a dearomatized, radical, ligand scaffold. This complex is an active catalyst for the hydrosilylation of esters to afford alcohols; loadings as low as 1 mol% were employed. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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