Evaluation of the potential of coal fly ash produced by gasification as hexavalent chromium adsorbent.

Autor: Ribeiro PB; Chemical Engineering, Federal University of Pampa, 1650 Maria Anunciação Gomes Godoy Avenue, Bagé, Rio Grande do Sul, 96413-172, Brazil., de Freitas VO; Chemical Engineering, Federal University of Rio Grande do Sul, 2777 Ramiro Barcelos Street, Porto Alegre, Rio Grande do Sul, 90035-007, Brazil., Machry K; Chemical Engineering, Federal University of Pampa, 1650 Maria Anunciação Gomes Godoy Avenue, Bagé, Rio Grande do Sul, 96413-172, Brazil., Muniz ARC; Chemical Engineering, Federal University of Pampa, 1650 Maria Anunciação Gomes Godoy Avenue, Bagé, Rio Grande do Sul, 96413-172, Brazil., da Rosa GS; Chemical Engineering, Federal University of Pampa, 1650 Maria Anunciação Gomes Godoy Avenue, Bagé, Rio Grande do Sul, 96413-172, Brazil. gabrielarosa@unipampa.edu.br.
Jazyk: angličtina
Zdroj: Environmental science and pollution research international [Environ Sci Pollut Res Int] 2019 Oct; Vol. 26 (28), pp. 28603-28613. Date of Electronic Publication: 2018 Dec 13.
DOI: 10.1007/s11356-018-3852-7
Abstrakt: The aim of this work was to characterize the coal fly ash from gasification process (G-CFA) and to analyze its potential as hexavalent chromium Cr (VI) adsorbent. The G-CFA was characterized in terms of physical, chemical, mineralogical, and morphological analyses. Bach adsorption studies were carried out in order to evaluate the influence of pH on the adsorption capacity and removal efficiency of Cr (VI). The G-CFA characterization demonstrated that the material possessed potential to be applied as an effective low-cost adsorbent, once it presents 18.82 m 2  g -1 , 0.036 cm 3 g -1 , and 7.56 nm of surface area, pore volume, and average pore diameter, respectively. The results also showed well-defined mineralogical phases and high content of siliceous material. The adsorption experiments demonstrated that the material has potential to be used as a chromium adsorbent with high removal efficiencies.
Databáze: MEDLINE