| Autor: |
Kaliannan D; Department of Environmental Science, School of Life Sciences, Periyar University, Salem, Tamil Nadu, 636011, India., Palaninaicker S; Department of Environmental Science, School of Life Sciences, Periyar University, Salem, Tamil Nadu, 636011, India. pskumares@gmail.com., Palanivel V; Department of Microbiology, Sri Sankara Arts and Science College, Enathur Road, Enathur, Tamil Nadu, 631561, India., Mahadeo MA; Division of Biotechnology, Safety, Environment and Life Science Institute, College of Environmental and Bioresource Sciences, Chonbuk National University, Iksan, 570-752, South Korea., Ravindra BN; School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeongbuk, 38541, South Korea., Jae-Jin S; School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeongbuk, 38541, South Korea. |
| Abstrakt: |
Saccharum officinarum leaves (SL) assisted nano-silica (NS) were synthesized and used as adsorbent to remove Pb 2+ and Zn 2+ from aqueous solutions. The crystalline nature, functional group, and morphology structure of synthesized NS were characterized by X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), field emission-scanning electron microscopy (FESEM) with EDS mapping, and transmission electron microscopy (TEM). The surface area and charge of the NS were also analyzed by Brunauer-Emmett-Teller (BET) and zeta potential analysis. Removal efficiency of Pb 2+ and Zn 2+ from aqueous solutions was carried out under batch mode studies (pH, dose, equilibrium time with initial heavy weight metal ion concentration). The adsorption parameters were determined using pseudo-first-order, pseudo-second-order, Langmuir, and Freundlich models. The kinetics and isotherms data were well fitted with pseudo-second-order and both Langmuir and Freundlich isotherm models. The maximum adsorption capacities for Pb 2+ and Zn 2+ onto NS at room temperature (37 °C) were found to be 148 mg/g and 137 mg/g, respectively. Finally, we conclude that the NS synthesized from SL leaves (agricultural waste material) were found to be economically viable, promising adsorbent for metal ions from aqueous solutions and also efficient technology for waste management. |
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