| Autor: |
Mayakrishnan S; Organic & Bioorganic Chemistry Laboratory, CSIR-Central Leather Research Institute, Chennai 600 020, Tamil Nadu, India. ptperumal@gmail.com umamaheswari@clri.res.in., Arun Y, Uma Maheswari N, Perumal PT |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Oct 18; Vol. 54 (84), pp. 11889-11892. |
| DOI: |
10.1039/c8cc07167e |
| Abstrakt: |
Rhodium-catalysed decarbonylative annulation of isatoic anhydrides with alkynes through C-H activation for the synthesis of aminoisocoumarins was developed. This enables the gram-scale transformation to iodoisocoumarin which is a vital building block in transition-metal-catalysed cross couplings. These compounds exhibit blue-emitting luminescence properties. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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