| Autor: |
Burns CP; Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX 77843, USA. nippe@chem.tamu.edu., Yang X, Sung S, Wofford JD, Bhuvanesh NS, Hall MB, Nippe M |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Sep 25; Vol. 54 (77), pp. 10893-10896. |
| DOI: |
10.1039/c8cc05243c |
| Abstrakt: |
The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp22- (PyCp22- = [2,6-(CH2C5H3)2C5H3N]2-) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce-Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy-Fe bonded species. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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